Handbook of olefin metathesis


Handbook of olefin metathesis

The three volumes are edited by the Nobel laureate Professor Robert H. Grubbs California Institute of Technology, USA in collaboration with an impressive panel of co-editors, all famous experts in the field.

Since the first edition several books, thematic issues and extensive reviews on metathesis reactions have appeared 2 — 8 and this new edition enormously adds to the present knowledge, representing the most important compendium of the state-of-the-art of alkene, alkane and alkyne metathesis and metathesis polymerisation, with a strong focus on the present research in this fascinating field of chemistry.

Metathesis has real potential for large scale valorisation in many industrial areas in the near future. Schrock Massachusetts Institute of Technology, USA authoritatively and attractively surveys high oxidation state molybdenum and tungsten complexes relevant to olefin metathesis.

Special attention is paid to the synthesis of novel imido ligands, bispyrrolide and related complexes, and to the appealing applications of monoalkoxide pyrrolide MAP complexes which are highly efficient in Z-selective olefin metathesis reactions homocoupling, cross-coupling, ethenolysis and ring-opening metathesis polymerisation ROMP.

Account Options Description Covering the complete breadth of the olefin metathesis reaction.
The latter are sufficiently active not to require any catalyst extraction, nor removal of atactic polymer because of the high stereospecificity.
Wiley-VCH - Handbook of Metathesis Grubbs of the California Institute of Technology. His pioneering work has led to the success of this important and fascinating reaction and in this comprehensive three-volume work he presents all its important aspects.
"Handbook of Metathesis" | eds. Grubb, Wenzel, O'Leary, Khosravi 2nd Ed It is notexaggerating if the advertisement forthe Handbook of Metathesis states thatthe team of authors reads like a Whoswho of metathesis. Katz, Amir Hoveyda, Jean-Marie Basset and Alois Furstner justto mention some of the authors tocompile a must-have for every organic,organometallic and polymer chemist.
Handbook of Polyolefins - Google Books Grubbs assembled Richard R.

The rich information offers deep insights into the mechanism and stereochemistry of metathesis reactions initiated by high oxidation state Mo and W complexes that have played a crucial role in the Handbook of olefin metathesis of olefin metathesis chemistry.

The potential for producing supported metal-alkylidene catalysts of Mo, Ta, W and their applications in alkane metathesis is fully illustrated. Keitz California Institute of Technology gives an interesting account of diastereocontrol in olefin metathesis when using Z-selective ruthenium catalysts.

This chapter concentrates on the fulminant development of Ru-based Z-selective metathesis catalysts as well as on a fresh mechanistic grasp specifically concerning the effects of N-heterocyclic carbenes NHC and of their substituents on reaction stereoselectivity and catalyst decomposition.

Catalyst preparation, characterisation and utilisation in RCM, CM, ethenolysis and degenerate metathesis are discussed. A particular challenge for the evolution of this type of catalysts is evidenced, namely the implementation of CAAC ligands for stereospecific control in asymmetric olefin metathesis and regiospecificity in ring expansion metathesis polymerisation.

Chapter 5 by Daryl P. Allen Materia Inc, USA is dedicated to supported catalysts and non-traditional reaction media, both issues of intense contemporary research.

Handbook of olefin metathesis

In the second part modern concepts of using non-traditional reaction media for example water, ionic liquids, fluorous systems are introduced. The assets of computational chemistry in terms of understanding at a molecular level and the recent advances in structure-reactivity relationships catalytic performance are revealed.

From another perspective Peng Liu, Buck L. Intermediates in the early and late transition metal-catalysed olefin metathesis, as investigated by X-ray crystallography and nuclear magnetic resonance NMR spectroscopy, are examined by Anna G.

Wenzel in Chapter 8.

“Handbook of Metathesis” 2nd Edition

New Insights on Olefin Metatheses How initiation rates play an essential role in olefin metatheses induced by Grubbs, Hoveyda-Grubbs, Piers and Herrmann catalysts or by indenylidene-Ru precatalysts is enticingly portrayed in Chapter 9 by Justin R.

Griffiths and Steven T. A detailed analysis of the main factors affecting the initial rates such as ligand dissociation and exchange, alkene coordination, and the nature of the catalyst and solvent is given. In the next chapter, the intriguing topic of degenerate metathesis reactions as promoted by heterogeneous and homogeneous, early- and late-transition metal catalytic systems, is reviewed by Ian C.

In order to obtain conclusive evidence on the mechanism of methylene exchange process, some selected metathesis reactions are screened using various isotopic-labelling experiments, in addition to pertinent stereochemical studies. In Chapter 11, Yann Schrodi California State University, Northridge, USA considers the most significant aspects of the mechanism of catalyst decomposition in olefin metathesis as well as specific methods for catalyst reactivation.

Along these lines, the decomposition mechanisms of very active and stereoselective Mo- and W-imido alkylidene complexes are elaborated followed by a report on the decomposition pathways of numerous classes of Ru-alkylidene complexes.

The information provided indicates different behaviour in the thermal decomposition for the first and second generation catalysts, particularly for Ru-alkylidene complexes.

Critical observations on catalyst stability, nature of intermediates and products of catalyst decomposition are advanced. The decomposition mechanism in the presence of functional groups or small molecules is also discussed.

Strategies for preventing catalyst decomposition and for extending catalyst life i. The crucial role played by the solvent and additives on catalyst activity and selectivity is thoroughly documented by Shawn K.

Collins University of Montreal, Canada in Chapter Examples include the effects of perfluoroaromatic solvents or additives such as alcohols that increase the initiation rates of metathesis reactions induced by Ru-based catalysts. In enyne metathesis promoted by Ru catalysts, the author convincingly shows that both activity and selectivity are strongly influenced when changing the reaction atmosphere from nitrogen to ethylene.

In numerous asymmetric metathesis reactions the reactivity and enantioselectivity can be strongly determined by halide salts in numerous asymmetric metathesis reactions.

Additives of the Lewis-acid type frequently promote macrocyclisations whereas other types of acid or base additives suppress olefin isomerisation favouring metathesis. Chapter 13 by David W.Handbook of Metathesis, Volume 3: Polymer Synthesis - Kindle edition by Robert H.

Grubbs, Ezat Khosravi. Download it once and read it on your Kindle device, PC, phones or tablets.

Volume 1: “Catalyst Development and Mechanism”

Use features like bookmarks, note taking and highlighting while reading Handbook of Metathesis, Volume 3: . Covering the complete breadth of the olefin metathesis reaction. The second edition of the ultimate reference in this field is completely updated and features more than 80% new content, with the focus on new developments in the field, especially in industrial metin2sell.com: Robert H.

Grubbs. The current chapter gives an overview on developments in the synthesis of homo- and co-polymers via ROMP which were disclosed after the first edition of the Handbook of Olefin .

Request PDF on ResearchGate | Handbook of Metathesis, Set | Olefin metathesis (OM) is one of the most versatile methods used to create carbon-carbon bonds in molecules. The synthetic strategies. Handbook of Metathesis, Volume 1: Catalyst Development and Mechanism / Edition 2 The second edition of the Handbook of Metathesis, edited by Nobel Prize Winner Robert H.

Grubbs and his team, is available as a 3 Volume set as well as individual metin2sell.com: $ Handbook of Metathesis, 3 volume set ISBN ISBN SDS Preface CATALYST DEVELOPMENTS Introduction The Role of the "Tebbe Complex" in Olefin Metathesis The Discovery and Development of High Oxidation State Mo and W Imido Alkylidene Complexes for Alkene Metathesis From ill-defined to well-defined W alkylidene.

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